Document Type : Original Article

Authors

1 American University of the Middle East

2 Department of Engineering Science, Faculty of Technology and Engineering, East of Guilan, University of Guilan, Rudsar-Vajargah, Iran

Abstract

The elastic modulus and Poisson’s ratio of polymer matrix nanocomposites (PMNCs) filled with graphene nanoplatelets (GNPs) are determined using an analytical micromechanical model. It is assumed that the GNPs are uniformly dispersed and randomly oriented into the polymer matrix. Due to the folded and wrinkled structure of GNPs, the effect of their flatness ratio on the elastic properties is investigated. Moreover, the micromechanical model captures the creation of interfacial region between the graphene and polymer matrix. The results show that addition of graphene particles into the polymer matrix can enhance the nanocomposite elastic modulus. Poisson’s ratio of polymer matrix increases with the increase of graphene content. It is observed that the elastic properties are decreased by the GNP non-flatness structure. Also, the material and dimensional characteristics of interfacial region affects the elastic modulus and Poisson’s ratio of GNP-reinforced PMNCs. The model predictions agree very well with the experimental data.

Keywords

[1].Li, Bin, and Wei-Hong Zhong. "Review on polymer/graphite nanoplatelet nanocomposites." Journal of materials science 46, no. 17 (2011): 5595-5614.
[2].Mittal, Vikas. "Functional polymer nanocomposites with graphene: a review." Macromolecular Materials and Engineering 299, no. 8 (2014): 906-931.
[3].Ma, Peng-Cheng, Naveed A. Siddiqui, Gad Marom, and Jang-Kyo Kim. "Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review." Composites Part A: Applied Science and Manufacturing 41, no. 10 (2010): 1345-1367.
[4].Saravanan, N., R. Rajasekar, S. Mahalakshmi, T. P. Sathishkumar, K. S. K. Sasikumar, and S. Sahoo. "Graphene and modified graphene-based polymer nanocomposites–a review." Journal of Reinforced Plastics and Composites 33, no. 12 (2014): 1158-1170.
[5].Wu, Gaohui, Zhenhe Yu, Longtao Jiang, Chang Zhou, Gong Deng, Xiaobing Deng, and Yunzhen Xiao. "A novel method for preparing graphene nanosheets/Al composites by accumulative extrusion-bonding process." Carbon 152 (2019): 932-945.
[6].Bhadauria, Alok, Lavish K. Singh, and Tapas Laha. "Effect of physio-chemically functionalized graphene nanoplatelet reinforcement on tensile properties of aluminum nanocomposite synthesized via spark plasma sintering." Journal of Alloys and Compounds 748 (2018): 783-793.
[7].King, Julia A., Danielle R. Klimek, Ibrahim Miskioglu, and Greg M. Odegard. "Mechanical properties of graphene nanoplatelet/epoxy composites." Journal of Composite Materials 49, no. 6 (2015): 659-668.
[8].Rafiee, Mohammad A., Javad Rafiee, Zhou Wang, Huaihe Song, Zhong-Zhen Yu, and Nikhil Koratkar. "Enhanced mechanical properties of nanocomposites at low graphene content." ACS nano 3, no. 12 (2009): 3884-3890.
[9].Hadden, Cameron M., Danielle R. Klimek-McDonald, Evan J. Pineda, Julie A. King, Alex M. Reichanadter, Ibrahim Miskioglu, S. Gowtham, and Gregory M. Odegard. "Mechanical properties of graphene nanoplatelet/carbon fiber/epoxy hybrid composites: Multiscale modeling and experiments." Carbon 95 (2015): 100-112.
[10].Wang, Zhenyu, Zhemin Jia, Xiaoping Feng, and Yun Zou. "Graphene nanoplatelets/epoxy composites with excellent shear properties for construction adhesives." Composites Part B: Engineering 152 (2018): 311-315.
[11].Suh, Jiyeon, and Donghyun Bae. "Mechanical properties of polytetrafluoroethylene composites reinforced with graphene nanoplatelets by solid-state processing." Composites Part B: Engineering 95 (2016): 317-323.
[12].Zhang, Yanli, Yan Wang, Junrong Yu, Lei Chen, Jing Zhu, and Zuming Hu. "Tuning the interface of graphene platelets/epoxy composites by the covalent grafting of polybenzimidazole." Polymer 55, no. 19 (2014): 4990-5000.
[13].Rafiee, Roham, and Amirali Eskandariyun. "Estimating Young's modulus of graphene/polymer composites using stochastic multi-scale modeling." Composites Part B: Engineering 173 (2019): 106842.
[14].Shokrieh, Z., M. M. Shokrieh, and Z. Zhao. "A modified micromechanical model to predict the creep modulus of polymeric nanocomposites." Polymer Testing 65 (2018): 414-419.
[15].Bakamal, A., R. Ansari, and M. K. Hassanzadeh-Aghdam. "Bending, free vibration, and buckling responses of chopped carbon fiber/graphene nanoplatelet-reinforced polymer hybrid composite plates: An inclusive microstructural assessment." Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science 235, no. 8 (2021): 1455-1469.
[16].Chu, Ke, Wen-sheng Li, and Fu-ling Tang. "Flatness-dependent thermal conductivity of graphene-based composites." Physics Letters A 377, no. 12 (2013): 910-914.
[17].Ji, Xiang-Ying, Yan-Ping Cao, and Xi-Qiao Feng. "Micromechanics prediction of the effective elastic moduli of graphene sheet-reinforced polymer nanocomposites." Modelling and Simulation in Materials Science and Engineering 18, no. 4 (2010): 045005.
[18].Pouyanmehr, R., M. K. Hassanzadeh-Aghdam, and R. Ansari. "Effect of graphene nanosheet dispersion on diffusion-induced stresses in layered sn-based nanocomposite electrode for lithium-ion batteries." Mechanics of Materials 145 (2020): 103390.
[19].Shokrieh, M. M., M. Esmkhani, Z. Shokrieh, and Z. Zhao. "Stiffness prediction of graphene nanoplatelet/epoxy nanocomposites by a combined molecular dynamics–micromechanics method." Computational materials science 92 (2014): 444-450.